Long-range and many-body effects in coagulation processes

We study the problem of diffusing particles which coalesce upon contact. With the aid of a nonperturbative renormalization group, we first analyze the dynamics emerging below the critical dimension two, where strong fluctuations imply anomalously slow decay. Above two dimensions, the long-time, low-density behavior is known to conform with the law of mass action. For this case, we establish an exact mapping between the physics at the microscopic scale (lattice structure, particle shape and size) and the macroscopic decay rate in the law of mass action. In addition, we identify a term violating this classical law. It originates in long-range and many-particle fluctuations and is a simple, universal function of the macroscopic decay rate. DOI: 10.1103/PhysRevE.87.02213

Statistical characterization of phenolic-novolak structures

Three statistical methods of general validity are valuable for characterizing any polymer which results from chain polymerization of multifunctional branching monomers linked through bifunctional monomers

First results of observations of transient pulsar SAXJ2103.5+4545 with the INTEGRAL observatory

We present preliminary results of observations of X-ray pulsar SAX J2103.5+4545 with INTEGRAL observatory in Dec 2002. Maps of this sky region in energy bands 3-10, 15-40, 40-100 and 100-200 keV are presented. The source is significantly detected up to energies of $\sim100$ keV. The hard X-ray flux in the 15-100 energy band is variable, that could be connected with the orbital phase of the binary system. We roughly reconstructed the source spectrum using its comparison to that of Crab nebula. It is shown that the parameters of the source spectrum in 18-150 keV energy range are compatible with that obtained earlier by RXTE observatoryComment: 5 pages, 4 figures, accepted for publication in the Astronomy Letter

Side-jumps in the spin-Hall effect: construction of the Boltzmann collision integral

We present a systematic derivation of the side-jump contribution to the spin-Hall current in systems without band structure spin-orbit interactions, focusing on the construction of the collision integral for the Boltzmann equation. Starting from the quantum Liouville equation for the density operator we derive an equation describing the dynamics of the density matrix in the first Born approximation and to first order in the driving electric field. Elastic scattering requires conservation of the total energy, including the spin-orbit interaction energy with the electric field: this results in a first correction to the customary collision integral found in the Born approximation. A second correction is due to the change in the carrier position during collisions. It stems from the part of the density matrix off-diagonal in wave vector. The two corrections to the collision integral add up and are responsible for the total side-jump contribution to the spin-Hall current. The spin-orbit-induced correction to the velocity operator also contains terms diagonal and off-diagonal in momentum space, which together involve the total force acting on the system. This force is explicitly shown to vanish (on the average) in the steady state: thus the total contribution to the spin-Hall current due to the additional terms in the velocity operator is zero.Comment: Added references, expanded discussion, revised introductio

Semiflexible polymers under external fields confined to two dimensions

The non-equilibrium structural and dynamical properties of semiflexible polymers confined to two dimensions are investigated by molecular dynamics simulations. Three different scenarios are considered: The force-extension relation of tethered polymers, the relaxation of an initially stretched semiflexible polymer, and semiflexible polymers under shear flow. We find quantitative agreement with theoretical predictions for the force-extension relation and the time dependence of the entropically contracting polymer. The semiflexible polymers under shear flow exhibit significant conformational changes at large shear rates, where less stiff polymers are extended by the flow, whereas rather stiff polymers are contracted. In addition, the polymers are aligned by the flow, thereby the two-dimensional semiflexible polymers behave similarly to flexible polymers in three dimensions. The tumbling times display a power-law dependence at high shear rate rates with an exponent comparable to the one of flexible polymers in three-dimensional systems.Comment: Accepted for publication in J. Chem. Phy